Templated synthesis, postsynthetic metal exchange, and properties of a porphyrin-encapsulating metal-organic material

Zhenjie Zhang; Linping Zhang; Lukasz Wojtas; Patrick Nugent; Mohamed Eddaoudi; Michael J. Zaworotko

doi:10.1021/ja209643b

Templated synthesis, postsynthetic metal exchange, and properties of a porphyrin-encapsulating metal-organic material

Zhenjie Zhang, Linping Zhang, Lukasz Wojtas, Patrick Nugent, Mohamed Eddaoudi, Michael J. Zaworotko

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of biphenyl-3,4′,5-tricarboxylate (H ₃BPT) and CdCl ₂ in the presence of meso-tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) afforded porph@MOM-10, a microporous metal-organic material containing CdTMPyP cations encapsulated in an anionic Cd(II) carboxylate framework, [Cd ₆(BPT) ₄Cl ₄(H ₂O) ₄]. Porph@MOM-10 is a versatile platform that undergoes exchange to serve as the parent of a series of porph@MOMs that exhibit permanent porosity and heterogeneous catalytic activity.

Original language	English
Pages (from-to)	924-927
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
Issue number	2
DOIs	https://doi.org/10.1021/ja209643b
Publication status	Published - 18 Jan 2012
Externally published	Yes

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title = "Templated synthesis, postsynthetic metal exchange, and properties of a porphyrin-encapsulating metal-organic material",

abstract = "Reaction of biphenyl-3,4′,5-tricarboxylate (H 3BPT) and CdCl 2 in the presence of meso-tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) afforded porph@MOM-10, a microporous metal-organic material containing CdTMPyP cations encapsulated in an anionic Cd(II) carboxylate framework, [Cd 6(BPT) 4Cl 4(H 2O) 4]. Porph@MOM-10 is a versatile platform that undergoes exchange to serve as the parent of a series of porph@MOMs that exhibit permanent porosity and heterogeneous catalytic activity.",

author = "Zhenjie Zhang and Linping Zhang and Lukasz Wojtas and Patrick Nugent and Mohamed Eddaoudi and Zaworotko, \{Michael J.\}",

year = "2012",

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doi = "10.1021/ja209643b",

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T1 - Templated synthesis, postsynthetic metal exchange, and properties of a porphyrin-encapsulating metal-organic material

AU - Zhang, Zhenjie

AU - Zhang, Linping

AU - Wojtas, Lukasz

AU - Nugent, Patrick

AU - Eddaoudi, Mohamed

AU - Zaworotko, Michael J.

PY - 2012/1/18

Y1 - 2012/1/18

N2 - Reaction of biphenyl-3,4′,5-tricarboxylate (H 3BPT) and CdCl 2 in the presence of meso-tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) afforded porph@MOM-10, a microporous metal-organic material containing CdTMPyP cations encapsulated in an anionic Cd(II) carboxylate framework, [Cd 6(BPT) 4Cl 4(H 2O) 4]. Porph@MOM-10 is a versatile platform that undergoes exchange to serve as the parent of a series of porph@MOMs that exhibit permanent porosity and heterogeneous catalytic activity.

AB - Reaction of biphenyl-3,4′,5-tricarboxylate (H 3BPT) and CdCl 2 in the presence of meso-tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) afforded porph@MOM-10, a microporous metal-organic material containing CdTMPyP cations encapsulated in an anionic Cd(II) carboxylate framework, [Cd 6(BPT) 4Cl 4(H 2O) 4]. Porph@MOM-10 is a versatile platform that undergoes exchange to serve as the parent of a series of porph@MOMs that exhibit permanent porosity and heterogeneous catalytic activity.

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DO - 10.1021/ja209643b

M3 - Article

AN - SCOPUS:84862907672

SN - 0002-7863

VL - 134

SP - 924

EP - 927

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 2

ER -

Templated synthesis, postsynthetic metal exchange, and properties of a porphyrin-encapsulating metal-organic material

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