The activity of supported vanadium oxide catalysts for the selective reduction of NO with ammonia

Hans Bosch; Frans J.J.G. Janssen; Frans M.G. van den Kerkhof; Jaap Oldenziel; Jan G. van Ommen; Julian R.H. Ross

doi:10.1016/S0166-9834(00)81242-7

The activity of supported vanadium oxide catalysts for the selective reduction of NO with ammonia

Hans Bosch, Frans J.J.G. Janssen, Frans M.G. van den Kerkhof, Jaap Oldenziel, Jan G. van Ommen, Julian R.H. Ross

Research output: Contribution to journal › Article › peer-review

Abstract

The activities of monolayer V₂O₅ catalysts for the selective reduction of NO with NH₃ are compared with those of commercial available catalysts containing V and/or W. From steady state and pulse experiments it can be concluded that the reduction of surface sites proceeds either by NH₃ + NO or by NH₃ alone. The reoxidation of the reduced sites occurs by gaseous oxygen or NO. The experimental reaction stoichiometry can be explained in terms of suitable combinations of these four reactions.

Original language	English
Pages (from-to)	239-248
Number of pages	10
Journal	Applied Catalysis
Volume	25
Issue number	1-2 C
DOIs	https://doi.org/10.1016/S0166-9834(00)81242-7
Publication status	Published - 15 Aug 1986
Externally published	Yes

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10.1016/S0166-9834(00)81242-7

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abstract = "The activities of monolayer V2O5 catalysts for the selective reduction of NO with NH3 are compared with those of commercial available catalysts containing V and/or W. From steady state and pulse experiments it can be concluded that the reduction of surface sites proceeds either by NH3 + NO or by NH3 alone. The reoxidation of the reduced sites occurs by gaseous oxygen or NO. The experimental reaction stoichiometry can be explained in terms of suitable combinations of these four reactions.",

author = "Hans Bosch and Janssen, {Frans J.J.G.} and {van den Kerkhof}, {Frans M.G.} and Jaap Oldenziel and {van Ommen}, {Jan G.} and Ross, {Julian R.H.}",

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AU - Bosch, Hans

AU - Janssen, Frans J.J.G.

AU - van den Kerkhof, Frans M.G.

AU - Oldenziel, Jaap

AU - van Ommen, Jan G.

AU - Ross, Julian R.H.

PY - 1986/8/15

Y1 - 1986/8/15

N2 - The activities of monolayer V2O5 catalysts for the selective reduction of NO with NH3 are compared with those of commercial available catalysts containing V and/or W. From steady state and pulse experiments it can be concluded that the reduction of surface sites proceeds either by NH3 + NO or by NH3 alone. The reoxidation of the reduced sites occurs by gaseous oxygen or NO. The experimental reaction stoichiometry can be explained in terms of suitable combinations of these four reactions.

AB - The activities of monolayer V2O5 catalysts for the selective reduction of NO with NH3 are compared with those of commercial available catalysts containing V and/or W. From steady state and pulse experiments it can be concluded that the reduction of surface sites proceeds either by NH3 + NO or by NH3 alone. The reoxidation of the reduced sites occurs by gaseous oxygen or NO. The experimental reaction stoichiometry can be explained in terms of suitable combinations of these four reactions.

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U2 - 10.1016/S0166-9834(00)81242-7

DO - 10.1016/S0166-9834(00)81242-7

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VL - 25

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JO - Applied Catalysis

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IS - 1-2 C

ER -

The activity of supported vanadium oxide catalysts for the selective reduction of NO with ammonia

Abstract

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