The influence of hydrothermal conditioning on the Mode-I, thermal and flexural properties of Carbon/Benzoxazine composites with a thermoplastic toughening interlayer

Carbon/Benzoxazine laminates with and without non-woven thermoplastic fibrous polyamide (PA) veils at the interlaminar regions were manufactured using Vacuum Assisted Resin Transfer Moulding (VARTM). The effect of the interlaminar thermoplastic veils on the Mode-I strain energy release rate (G_IC), flexural stiffness, glass transition temperature (T_g) and water absorption behaviour was determined using two commercially available Benzoxazine resins. Despite an increase in the maximum moisture content, the veils greatly enhanced G_IC by an increase in fibre bridging of PA fibres, with concurrent reductions in flexural stiffness. Water ingress resulted in large reductions in the T_g, although no significant change was observed due to the PA interlayers. Fibre bridging and fibre pull-out were the main mechanisms by which the veils assisted in resisting delamination. The presence of the water was observed to degrade mechanical properties due to a reduction in fibre/matrix interfacial strength, molecular degradation and plasticisation of the matrix.