The intergranular oxynitride microstructure in silicon nitride based ceramics

L. K.L. Falk, N. Schneider, Y. Menke, S. Hampshire

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

The intergranular microstructure in a liquid phase sintered silicon nitride based ceramic may be viewed as an oxynitride glass-ceramic. This work is concerned with the incorporation of yttrium B-phase, which is a five-component phase, into the intergranular regions of silicon nitride ceramics. The silicon nitride materials were fabricated with the addition of a powdered B-phase parent glass with composition (e/o) 35Y:45Si:20Al:83O:17N, or the addition of a mixture of Y2O3, SiO2 and Al2O 3 with cation composition (e/o) 35Y:45Si:20Al. The starting powder mixtures contained 10 wt% of sintering additives. Sintering for 2 h at 1800°C was followed by a two-step post-densification heat treatment in order to promote nucleation and growth of yttrium B-phase. Detailed imaging and elemental analysis of the intergranular regions was carried out by EDX in a FEGTEM.

Original languageEnglish
Title of host publicationNitrides and Oxynitrides III - Proceedings of the 5th International Symposium on Nitrides
PublisherTrans Tech Publications Ltd
Pages113-118
Number of pages6
ISBN (Print)0878494391, 9780878494392
DOIs
Publication statusPublished - 2007
Event5th International Symposium on Nitrides - Eskisehir, Turkey
Duration: 3 Apr 20065 Apr 2006

Publication series

NameMaterials Science Forum
Volume554
ISSN (Print)0255-5476
ISSN (Electronic)1662-9752

Conference

Conference5th International Symposium on Nitrides
Country/TerritoryTurkey
CityEskisehir
Period3/04/065/04/06

Keywords

  • B-phase
  • EDX
  • Intergranular microstructure
  • TEM

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