TY - JOUR
T1 - The phosphinomethylsilyl group as a bifunctional bridging ligand. X-ray crystal structure of hexacarbonylbis(μ-diphenylphosphinomethyldimethylsilyl) diruthenium(II), and of its reaction product with trifluoroacetic acid, a mononuclear ruthenium(II) complex incorporating a unique co-ordinated silanol
AU - Auburn, Mary J.
AU - Holmes-Smith, Rupert D.
AU - Stobart, Stephen R.
AU - Zaworotko, Michael J.
AU - Cameron, T. Stanley
AU - Kumari, Amrita
PY - 1983
Y1 - 1983
N2 - Reaction between Ru3(CO)12 and Ph2PCH 2SiMe2H affords the symmetrical bridged diruthenium complex [Ru2(μ-PPh2CH2SiMe2) 2(CO)6] in which Ru-Ru = 3.056(1) Å; treatment of this dimer with CF3CO2H leads to formation of a mononuclear phosphinomethyldimethylsilanol complex [Ru(PPh2CH 2SiMe2OH)(CO)2(CO2CF 3)2·Et2O] in which Ru-OSi = 2.19 Å, δ(OH) = 12.12, and the solvating Et2O molecule is H-bonded to the silanol-O with O ⋯ O 2.64 Å.
AB - Reaction between Ru3(CO)12 and Ph2PCH 2SiMe2H affords the symmetrical bridged diruthenium complex [Ru2(μ-PPh2CH2SiMe2) 2(CO)6] in which Ru-Ru = 3.056(1) Å; treatment of this dimer with CF3CO2H leads to formation of a mononuclear phosphinomethyldimethylsilanol complex [Ru(PPh2CH 2SiMe2OH)(CO)2(CO2CF 3)2·Et2O] in which Ru-OSi = 2.19 Å, δ(OH) = 12.12, and the solvating Et2O molecule is H-bonded to the silanol-O with O ⋯ O 2.64 Å.
UR - http://www.scopus.com/inward/record.url?scp=37049099106&partnerID=8YFLogxK
U2 - 10.1039/C39830001523
DO - 10.1039/C39830001523
M3 - Article
AN - SCOPUS:37049099106
SN - 0022-4936
SP - 1523
EP - 1525
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 24
ER -