The phosphinomethylsilyl group as a bifunctional bridging ligand. X-ray crystal structure of hexacarbonylbis(μ-diphenylphosphinomethyldimethylsilyl) diruthenium(II), and of its reaction product with trifluoroacetic acid, a mononuclear ruthenium(II) complex incorporating a unique co-ordinated silanol

Mary J. Auburn; Rupert D. Holmes-Smith; Stephen R. Stobart; Michael J. Zaworotko; T. Stanley Cameron; Amrita Kumari

doi:10.1039/C39830001523

The phosphinomethylsilyl group as a bifunctional bridging ligand. X-ray crystal structure of hexacarbonylbis(μ-diphenylphosphinomethyldimethylsilyl) diruthenium(II), and of its reaction product with trifluoroacetic acid, a mononuclear ruthenium(II) complex incorporating a unique co-ordinated silanol

Mary J. Auburn
, Rupert D. Holmes-Smith
, Stephen R. Stobart
, Michael J. Zaworotko
, T. Stanley Cameron
, Amrita Kumari

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction between Ru₃(CO)₁₂ and Ph₂PCH ₂SiMe₂H affords the symmetrical bridged diruthenium complex [Ru₂(μ-PPh₂CH₂SiMe₂) ₂(CO)₆] in which Ru-Ru = 3.056(1) Å; treatment of this dimer with CF₃CO₂H leads to formation of a mononuclear phosphinomethyldimethylsilanol complex [Ru(PPh₂CH ₂SiMe₂OH)(CO)₂(CO₂CF ₃)₂·Et₂O] in which Ru-O_Si = 2.19 Å, δ(OH) = 12.12, and the solvating Et₂O molecule is H-bonded to the silanol-O with O ⋯ O 2.64 Å.

Original language	English
Pages (from-to)	1523-1525
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/C39830001523
Publication status	Published - 1983
Externally published	Yes

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Auburn, M. J., Holmes-Smith, R. D., Stobart, S. R., Zaworotko, M. J., Cameron, T. S., & Kumari, A. (1983). The phosphinomethylsilyl group as a bifunctional bridging ligand. X-ray crystal structure of hexacarbonylbis(μ-diphenylphosphinomethyldimethylsilyl) diruthenium(II), and of its reaction product with trifluoroacetic acid, a mononuclear ruthenium(II) complex incorporating a unique co-ordinated silanol. Journal of the Chemical Society, Chemical Communications, (24), 1523-1525. https://doi.org/10.1039/C39830001523

Auburn, Mary J. ; Holmes-Smith, Rupert D. ; Stobart, Stephen R. et al. / The phosphinomethylsilyl group as a bifunctional bridging ligand. X-ray crystal structure of hexacarbonylbis(μ-diphenylphosphinomethyldimethylsilyl) diruthenium(II), and of its reaction product with trifluoroacetic acid, a mononuclear ruthenium(II) complex incorporating a unique co-ordinated silanol. In: Journal of the Chemical Society, Chemical Communications. 1983 ; No. 24. pp. 1523-1525.

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title = "The phosphinomethylsilyl group as a bifunctional bridging ligand. X-ray crystal structure of hexacarbonylbis(μ-diphenylphosphinomethyldimethylsilyl) diruthenium(II), and of its reaction product with trifluoroacetic acid, a mononuclear ruthenium(II) complex incorporating a unique co-ordinated silanol",

abstract = "Reaction between Ru3(CO)12 and Ph2PCH 2SiMe2H affords the symmetrical bridged diruthenium complex [Ru2(μ-PPh2CH2SiMe2) 2(CO)6] in which Ru-Ru = 3.056(1) {\AA}; treatment of this dimer with CF3CO2H leads to formation of a mononuclear phosphinomethyldimethylsilanol complex [Ru(PPh2CH 2SiMe2OH)(CO)2(CO2CF 3)2·Et2O] in which Ru-OSi = 2.19 {\AA}, δ(OH) = 12.12, and the solvating Et2O molecule is H-bonded to the silanol-O with O ⋯ O 2.64 {\AA}.",

author = "Auburn, \{Mary J.\} and Holmes-Smith, \{Rupert D.\} and Stobart, \{Stephen R.\} and Zaworotko, \{Michael J.\} and Cameron, \{T. Stanley\} and Amrita Kumari",

year = "1983",

doi = "10.1039/C39830001523",

language = "English",

pages = "1523--1525",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

number = "24",

}

Auburn, MJ, Holmes-Smith, RD, Stobart, SR, Zaworotko, MJ, Cameron, TS & Kumari, A 1983, 'The phosphinomethylsilyl group as a bifunctional bridging ligand. X-ray crystal structure of hexacarbonylbis(μ-diphenylphosphinomethyldimethylsilyl) diruthenium(II), and of its reaction product with trifluoroacetic acid, a mononuclear ruthenium(II) complex incorporating a unique co-ordinated silanol', Journal of the Chemical Society, Chemical Communications, no. 24, pp. 1523-1525. https://doi.org/10.1039/C39830001523

The phosphinomethylsilyl group as a bifunctional bridging ligand. X-ray crystal structure of hexacarbonylbis(μ-diphenylphosphinomethyldimethylsilyl) diruthenium(II), and of its reaction product with trifluoroacetic acid, a mononuclear ruthenium(II) complex incorporating a unique co-ordinated silanol. / Auburn, Mary J.; Holmes-Smith, Rupert D.; Stobart, Stephen R. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 24, 1983, p. 1523-1525.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - The phosphinomethylsilyl group as a bifunctional bridging ligand. X-ray crystal structure of hexacarbonylbis(μ-diphenylphosphinomethyldimethylsilyl) diruthenium(II), and of its reaction product with trifluoroacetic acid, a mononuclear ruthenium(II) complex incorporating a unique co-ordinated silanol

AU - Auburn, Mary J.

AU - Holmes-Smith, Rupert D.

AU - Stobart, Stephen R.

AU - Zaworotko, Michael J.

AU - Cameron, T. Stanley

AU - Kumari, Amrita

PY - 1983

Y1 - 1983

N2 - Reaction between Ru3(CO)12 and Ph2PCH 2SiMe2H affords the symmetrical bridged diruthenium complex [Ru2(μ-PPh2CH2SiMe2) 2(CO)6] in which Ru-Ru = 3.056(1) Å; treatment of this dimer with CF3CO2H leads to formation of a mononuclear phosphinomethyldimethylsilanol complex [Ru(PPh2CH 2SiMe2OH)(CO)2(CO2CF 3)2·Et2O] in which Ru-OSi = 2.19 Å, δ(OH) = 12.12, and the solvating Et2O molecule is H-bonded to the silanol-O with O ⋯ O 2.64 Å.

AB - Reaction between Ru3(CO)12 and Ph2PCH 2SiMe2H affords the symmetrical bridged diruthenium complex [Ru2(μ-PPh2CH2SiMe2) 2(CO)6] in which Ru-Ru = 3.056(1) Å; treatment of this dimer with CF3CO2H leads to formation of a mononuclear phosphinomethyldimethylsilanol complex [Ru(PPh2CH 2SiMe2OH)(CO)2(CO2CF 3)2·Et2O] in which Ru-OSi = 2.19 Å, δ(OH) = 12.12, and the solvating Et2O molecule is H-bonded to the silanol-O with O ⋯ O 2.64 Å.

UR - https://www.scopus.com/pages/publications/37049099106

U2 - 10.1039/C39830001523

DO - 10.1039/C39830001523

M3 - Article

AN - SCOPUS:37049099106

SN - 0022-4936

SP - 1523

EP - 1525

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 24

ER -

Auburn MJ, Holmes-Smith RD, Stobart SR, Zaworotko MJ, Cameron TS, Kumari A. The phosphinomethylsilyl group as a bifunctional bridging ligand. X-ray crystal structure of hexacarbonylbis(μ-diphenylphosphinomethyldimethylsilyl) diruthenium(II), and of its reaction product with trifluoroacetic acid, a mononuclear ruthenium(II) complex incorporating a unique co-ordinated silanol. Journal of the Chemical Society, Chemical Communications. 1983;(24):1523-1525. doi: 10.1039/C39830001523

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