TY - JOUR
T1 - Three porphyrin-encapsulating metal-organic materials with ordered metalloporphyrin moieties
AU - Zhang, Zhenjie
AU - Wojtas, Lukasz
AU - Zaworotko, Michael J.
PY - 2014/4/2
Y1 - 2014/4/2
N2 - 1,3,5-benzenetricarboxylate, biphenyl-3,4′,5-tricarboxylate, and [1,1′:3′,1″-terphenyl]-4,4″,5′-tricarboxylate react with Cd(II) cations in the presence of meso-tetra(N-methyl-4-pyridyl) porphine cations to afford three metalloporphyrin-encapsulating metal-organic materials, porph@MOM-11, -12 and -13, respectively. The metalloporphyrin moieties are ordered within channels and closely fit hexagonal or rectangular cavities, thereby facilitating a better understanding of the structure-directing effect that can be promoted by metalloporphyrins. Porph@MOM-12 is noteworthy because it exhibits two distinct types of hexagonal channels and it represents the first example of a net that exhibits mzz topology.
AB - 1,3,5-benzenetricarboxylate, biphenyl-3,4′,5-tricarboxylate, and [1,1′:3′,1″-terphenyl]-4,4″,5′-tricarboxylate react with Cd(II) cations in the presence of meso-tetra(N-methyl-4-pyridyl) porphine cations to afford three metalloporphyrin-encapsulating metal-organic materials, porph@MOM-11, -12 and -13, respectively. The metalloporphyrin moieties are ordered within channels and closely fit hexagonal or rectangular cavities, thereby facilitating a better understanding of the structure-directing effect that can be promoted by metalloporphyrins. Porph@MOM-12 is noteworthy because it exhibits two distinct types of hexagonal channels and it represents the first example of a net that exhibits mzz topology.
UR - http://www.scopus.com/inward/record.url?scp=84897522874&partnerID=8YFLogxK
U2 - 10.1021/cg500192d
DO - 10.1021/cg500192d
M3 - Article
AN - SCOPUS:84897522874
SN - 1528-7483
VL - 14
SP - 1526
EP - 1530
JO - Crystal Growth and Design
JF - Crystal Growth and Design
IS - 4
ER -