Two homochiral organocatalytic metal organic materials with nanoscopic channels

Zhuxiu Zhang, Young Ran Ji, Lukasz Wojtas, Wen Yang Gao, Shengqian Ma, Michael J. Zaworotko, Jon C. Antilla

Research output: Contribution to journalArticlepeer-review

Abstract

Two homochiral organocatalytic MOMs were prepared using tetra- and octa-carboxylate ligands, respectively. The nanoscopic channels in these MOMs are lined by organonocatalytic chiral phosphoric acid derivatives of binol and ocMOM-1 exhibited improved enantioselectivity over the parent ligand in the context of transfer hydrogenation of a series of benzoxazines.

Original languageEnglish
Pages (from-to)7693-7695
Number of pages3
JournalChemical Communications
Volume49
Issue number70
DOIs
Publication statusPublished - 6 Aug 2013
Externally publishedYes

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