Abstract
Two porous nets have been prepared via a 2-step crystal engineering approach that links decorated trigonal prismatic [Cr3(μ3-O)(CO2)6] and [Cu3(μ3-Cl)(RNH2)6Cl6] molecular building blocks, MBBs. tp-PMBB-5-acs-1 is a rare example of a rigid acs underlying net whereas tp-PMBB-6-stp-1, an stp underlying net, exhibits free NH2 groups in its channels and a relatively high isosteric heat of adsorption for CO2.
Original language | English |
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Pages (from-to) | 8154-8156 |
Number of pages | 3 |
Journal | Chemical Communications |
Volume | 49 |
Issue number | 74 |
DOIs | |
Publication status | Published - 20 Aug 2013 |
Externally published | Yes |