Two-step crystal engineering of porous nets from [Cr3(μ3-O)(RCO2)6] and [Cu3(μ3-Cl)(RNH2)6Cl6] molecular building blocks

Sameh K. Elsaidi; Mona H. Mohamed; Lukasz Wojtas; Amy J. Cairns; Mohamed Eddaoudi; Michael J. Zaworotko

doi:10.1039/c3cc44133d

Two-step crystal engineering of porous nets from [Cr₃(μ₃-O)(RCO₂)₆] and [Cu₃(μ₃-Cl)(RNH₂)₆Cl₆] molecular building blocks

Sameh K. Elsaidi, Mona H. Mohamed, Lukasz Wojtas, Amy J. Cairns, Mohamed Eddaoudi, Michael J. Zaworotko

Research output: Contribution to journal › Article › peer-review

Abstract

Two porous nets have been prepared via a 2-step crystal engineering approach that links decorated trigonal prismatic [Cr₃(μ₃-O)(CO₂)₆] and [Cu₃(μ₃-Cl)(RNH₂)₆Cl₆] molecular building blocks, MBBs. tp-PMBB-5-acs-1 is a rare example of a rigid acs underlying net whereas tp-PMBB-6-stp-1, an stp underlying net, exhibits free NH₂ groups in its channels and a relatively high isosteric heat of adsorption for CO₂.

Original language	English
Pages (from-to)	8154-8156
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	74
DOIs	https://doi.org/10.1039/c3cc44133d
Publication status	Published - 20 Aug 2013
Externally published	Yes

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title = "Two-step crystal engineering of porous nets from [Cr3(μ3-O)(RCO2)6] and [Cu3(μ3-Cl)(RNH2)6Cl6] molecular building blocks",

abstract = "Two porous nets have been prepared via a 2-step crystal engineering approach that links decorated trigonal prismatic [Cr3(μ3-O)(CO2)6] and [Cu3(μ3-Cl)(RNH2)6Cl6] molecular building blocks, MBBs. tp-PMBB-5-acs-1 is a rare example of a rigid acs underlying net whereas tp-PMBB-6-stp-1, an stp underlying net, exhibits free NH2 groups in its channels and a relatively high isosteric heat of adsorption for CO2.",

author = "Elsaidi, \{Sameh K.\} and Mohamed, \{Mona H.\} and Lukasz Wojtas and Cairns, \{Amy J.\} and Mohamed Eddaoudi and Zaworotko, \{Michael J.\}",

year = "2013",

month = aug,

day = "20",

doi = "10.1039/c3cc44133d",

language = "English",

volume = "49",

pages = "8154--8156",

journal = "Chemical Communications",

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T1 - Two-step crystal engineering of porous nets from [Cr3(μ3-O)(RCO2)6] and [Cu3(μ3-Cl)(RNH2)6Cl6] molecular building blocks

AU - Elsaidi, Sameh K.

AU - Mohamed, Mona H.

AU - Wojtas, Lukasz

AU - Cairns, Amy J.

AU - Eddaoudi, Mohamed

AU - Zaworotko, Michael J.

PY - 2013/8/20

Y1 - 2013/8/20

N2 - Two porous nets have been prepared via a 2-step crystal engineering approach that links decorated trigonal prismatic [Cr3(μ3-O)(CO2)6] and [Cu3(μ3-Cl)(RNH2)6Cl6] molecular building blocks, MBBs. tp-PMBB-5-acs-1 is a rare example of a rigid acs underlying net whereas tp-PMBB-6-stp-1, an stp underlying net, exhibits free NH2 groups in its channels and a relatively high isosteric heat of adsorption for CO2.

AB - Two porous nets have been prepared via a 2-step crystal engineering approach that links decorated trigonal prismatic [Cr3(μ3-O)(CO2)6] and [Cu3(μ3-Cl)(RNH2)6Cl6] molecular building blocks, MBBs. tp-PMBB-5-acs-1 is a rare example of a rigid acs underlying net whereas tp-PMBB-6-stp-1, an stp underlying net, exhibits free NH2 groups in its channels and a relatively high isosteric heat of adsorption for CO2.

UR - https://www.scopus.com/pages/publications/84882621684

U2 - 10.1039/c3cc44133d

DO - 10.1039/c3cc44133d

M3 - Article

C2 - 23925067

AN - SCOPUS:84882621684

SN - 1359-7345

VL - 49

SP - 8154

EP - 8156

JO - Chemical Communications

JF - Chemical Communications

IS - 74

ER -

Two-step crystal engineering of porous nets from [Cr₃(μ₃-O)(RCO₂)₆] and [Cu₃(μ₃-Cl)(RNH₂)₆Cl₆] molecular building blocks

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