Two-step solid-state synthesis of PEPPSI-type compounds

Christopher J. Adams; Matteo Lusi; Emily M. Mutambi; A. Guy Orpen

doi:10.1039/c5cc02924d

Two-step solid-state synthesis of PEPPSI-type compounds

Christopher J. Adams, Matteo Lusi, Emily M. Mutambi, A. Guy Orpen

Department of Chemical Sciences

University of Limerick

Research output: Contribution to journal › Article › peer-review

Abstract

The two-step mechanochemical preparation of carbene-pyridine complexes of palladium and platinum is reported. The organometallic products, which represent a class of commercially available catalysts, are rapidly formed in excellent yield proving solvent-free synthesis to be a viable synthetic alternative even in the case of NHC-containing compounds.

Original language	English
Pages (from-to)	9632-9635
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	47
DOIs	https://doi.org/10.1039/c5cc02924d
Publication status	Published - 14 Jun 2015

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title = "Two-step solid-state synthesis of PEPPSI-type compounds",

abstract = "The two-step mechanochemical preparation of carbene-pyridine complexes of palladium and platinum is reported. The organometallic products, which represent a class of commercially available catalysts, are rapidly formed in excellent yield proving solvent-free synthesis to be a viable synthetic alternative even in the case of NHC-containing compounds.",

author = "Adams, {Christopher J.} and Matteo Lusi and Mutambi, {Emily M.} and Orpen, {A. Guy}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

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language = "English",

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AU - Adams, Christopher J.

AU - Lusi, Matteo

AU - Mutambi, Emily M.

AU - Orpen, A. Guy

N1 - Publisher Copyright: © The Royal Society of Chemistry 2015.

PY - 2015/6/14

Y1 - 2015/6/14

N2 - The two-step mechanochemical preparation of carbene-pyridine complexes of palladium and platinum is reported. The organometallic products, which represent a class of commercially available catalysts, are rapidly formed in excellent yield proving solvent-free synthesis to be a viable synthetic alternative even in the case of NHC-containing compounds.

AB - The two-step mechanochemical preparation of carbene-pyridine complexes of palladium and platinum is reported. The organometallic products, which represent a class of commercially available catalysts, are rapidly formed in excellent yield proving solvent-free synthesis to be a viable synthetic alternative even in the case of NHC-containing compounds.

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U2 - 10.1039/c5cc02924d

DO - 10.1039/c5cc02924d

M3 - Article

AN - SCOPUS:85002514627

SN - 1359-7345

VL - 51

SP - 9632

EP - 9635

JO - Chemical Communications

JF - Chemical Communications

IS - 47

ER -

Two-step solid-state synthesis of PEPPSI-type compounds

Abstract

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