Unprecedented mechanochemical preparation of 18Crown[6] and 15Crown[5] adducts of ammonium hydrogen sulfate by grinding or kneading

Dario Braga; Marco Curzi; Matteo Lusi; Fabrizia Grepioni

doi:10.1039/b504459f

Unprecedented mechanochemical preparation of 18Crown[6] and 15Crown[5] adducts of ammonium hydrogen sulfate by grinding or kneading

Dario Braga, Marco Curzi, Matteo Lusi, Fabrizia Grepioni

University of Bologna

Research output: Contribution to journal › Article › peer-review

Abstract

The complex 18Crown[6]Â•[NH₄][HSO₄] Â•2H₂O has been prepared by co-grinding of solid 18Crown[6] ether and solid [NH₄][HSO₄], while the complex (15Crown[5])₃Â•[NH₄]₂[H ₃O][HSO₄]₃Â•H₂O has been obtained by kneading liquid 15Crown[5] together with solid [NH ₄][HSO₄]. Structural characterization has been achieved on single crystals obtained by recrystallization of the solid products from water.

Original language	English
Article number	44
Pages (from-to)	276-278
Number of pages	3
Journal	CrystEngComm
Volume	7
DOIs	https://doi.org/10.1039/b504459f
Publication status	Published - 6 Apr 2005
Externally published	Yes

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title = "Unprecedented mechanochemical preparation of 18Crown[6] and 15Crown[5] adducts of ammonium hydrogen sulfate by grinding or kneading",

abstract = "The complex 18Crown[6]{\^A}•[NH4][HSO4] {\^A}•2H2O has been prepared by co-grinding of solid 18Crown[6] ether and solid [NH4][HSO4], while the complex (15Crown[5])3{\^A}•[NH4]2[H 3O][HSO4]3{\^A}•H2O has been obtained by kneading liquid 15Crown[5] together with solid [NH 4][HSO4]. Structural characterization has been achieved on single crystals obtained by recrystallization of the solid products from water.",

author = "Dario Braga and Marco Curzi and Matteo Lusi and Fabrizia Grepioni",

year = "2005",

month = apr,

day = "6",

doi = "10.1039/b504459f",

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journal = "CrystEngComm",

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T1 - Unprecedented mechanochemical preparation of 18Crown[6] and 15Crown[5] adducts of ammonium hydrogen sulfate by grinding or kneading

AU - Braga, Dario

AU - Curzi, Marco

AU - Lusi, Matteo

AU - Grepioni, Fabrizia

PY - 2005/4/6

Y1 - 2005/4/6

N2 - The complex 18Crown[6]Â•[NH4][HSO4] Â•2H2O has been prepared by co-grinding of solid 18Crown[6] ether and solid [NH4][HSO4], while the complex (15Crown[5])3Â•[NH4]2[H 3O][HSO4]3Â•H2O has been obtained by kneading liquid 15Crown[5] together with solid [NH 4][HSO4]. Structural characterization has been achieved on single crystals obtained by recrystallization of the solid products from water.

AB - The complex 18Crown[6]Â•[NH4][HSO4] Â•2H2O has been prepared by co-grinding of solid 18Crown[6] ether and solid [NH4][HSO4], while the complex (15Crown[5])3Â•[NH4]2[H 3O][HSO4]3Â•H2O has been obtained by kneading liquid 15Crown[5] together with solid [NH 4][HSO4]. Structural characterization has been achieved on single crystals obtained by recrystallization of the solid products from water.

UR - http://www.scopus.com/inward/record.url?scp=19444372401&partnerID=8YFLogxK

U2 - 10.1039/b504459f

DO - 10.1039/b504459f

M3 - Article

AN - SCOPUS:19444372401

SN - 1466-8033

VL - 7

SP - 276

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JO - CrystEngComm

JF - CrystEngComm

M1 - 44

ER -

Unprecedented mechanochemical preparation of 18Crown[6] and 15Crown[5] adducts of ammonium hydrogen sulfate by grinding or kneading

Abstract

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