TY - JOUR
T1 - Upgrading of a rare earth phosphate concentrate within the nitrophosphate process
AU - Alemrajabi, Mahmood
AU - Rasmuson, Åke C.
AU - Korkmaz, Kivanc
AU - Forsberg, Kerstin
N1 - Publisher Copyright:
© 2018 Elsevier Ltd
PY - 2018/10/10
Y1 - 2018/10/10
N2 - In the nitrophosphate process of fertilizer production, rare earth elements (REE) can be recovered as a REE phosphate concentrate. In this process, after digestion of apatite in concentrated nitric acid, Ca(NO3)2.4H2O is first separated by cooling crystallization and then the REE are precipitated in phosphate form by a partial neutralization step using ammonia. The obtained REE phosphate concentrate is contaminated by mainly calcium and iron, and the main solid phases are CaHPO4.2H2O, FePO4.2H2O and REEPO4.nH2O. In this study, a process to obtain a concentrate more enriched with REE with low concentration of calcium and iron and free of phosphorous is developed. In the developed process, enrichment and dephosphorization of the rare earth phosphate concentrate has been achieved by selective dissolution and re-precipitation of the REE as a sodium REE double sulfate salt. It is shown that by selective dissolution of the REE concentrate in nitric acid at a pH of 2.4, most of the calcium and phosphorus are dissolved, and a solid phase more enriched in REE is obtained. Thereafter, the REE phosphate concentrate is first dissolved in a mixture of sulfuric-phosphoric acid and then the REE are reprecipitated as NaREE(SO4)2.H2O by addition of a sodium salt. More than 95% of the Ca, Fe and P are removed and a REE concentrate containing almost 30 mass% total REE is obtained.
AB - In the nitrophosphate process of fertilizer production, rare earth elements (REE) can be recovered as a REE phosphate concentrate. In this process, after digestion of apatite in concentrated nitric acid, Ca(NO3)2.4H2O is first separated by cooling crystallization and then the REE are precipitated in phosphate form by a partial neutralization step using ammonia. The obtained REE phosphate concentrate is contaminated by mainly calcium and iron, and the main solid phases are CaHPO4.2H2O, FePO4.2H2O and REEPO4.nH2O. In this study, a process to obtain a concentrate more enriched with REE with low concentration of calcium and iron and free of phosphorous is developed. In the developed process, enrichment and dephosphorization of the rare earth phosphate concentrate has been achieved by selective dissolution and re-precipitation of the REE as a sodium REE double sulfate salt. It is shown that by selective dissolution of the REE concentrate in nitric acid at a pH of 2.4, most of the calcium and phosphorus are dissolved, and a solid phase more enriched in REE is obtained. Thereafter, the REE phosphate concentrate is first dissolved in a mixture of sulfuric-phosphoric acid and then the REE are reprecipitated as NaREE(SO4)2.H2O by addition of a sodium salt. More than 95% of the Ca, Fe and P are removed and a REE concentrate containing almost 30 mass% total REE is obtained.
KW - Nitrophosphate process
KW - Precipitation
KW - REE
KW - Selective dissolution
KW - Sodium REE double sulfate
UR - http://www.scopus.com/inward/record.url?scp=85053137761&partnerID=8YFLogxK
U2 - 10.1016/j.jclepro.2018.06.242
DO - 10.1016/j.jclepro.2018.06.242
M3 - Article
AN - SCOPUS:85053137761
SN - 0959-6526
VL - 198
SP - 551
EP - 563
JO - Journal of Cleaner Production
JF - Journal of Cleaner Production
ER -