Weak intermetallic bonding. A rare example of molecular stacking in a neutral square-planar second-row transition-metal complex. X-ray crystal structures of [Rh(cod)(Cl)(dmpH)] and [Rh(CO)2(Cl)(pzH)] (cod = cyclo-octa-1,5-diene; dmpH = 3,5-dimethylpyrazole; pzH = pyrazole)

Michael J. Decker; D. O.Kimberley Fjeldsted; Stephen R. Stobart; Michael J. Zaworotko

doi:10.1039/c39830001525

Weak intermetallic bonding. A rare example of molecular stacking in a neutral square-planar second-row transition-metal complex. X-ray crystal structures of [Rh(cod)(Cl)(dmpH)] and [Rh(CO)₂(Cl)(pzH)] (cod = cyclo-octa-1,5-diene; dmpH = 3,5-dimethylpyrazole; pzH = pyrazole)

Michael J. Decker
, D. O.Kimberley Fjeldsted
, Stephen R. Stobart
, Michael J. Zaworotko

University of Victoria BC

Research output: Contribution to journal › Article › peer-review

Abstract

The molecular geometry of [Rh(cod)(Cl)(dmpH)] (cod = cyclo-octa-1,5-diene; dmpH = 3,5-dimethylpyrazole) is normal in all respects with the heterocycle almost perpendicular to the Rh co-ordination plane and intermolecular Rh ⋯ Rh 4.49 Å; by contrast the crystal structure of [Rh(CO) ₂(Cl)(pzH)] (pzH = pyrazole) provides a classic example of molecular 'stacking', with Rh-Rh long at 3.4522(4) Å along the one-dimensional chain.

Original language	English
Pages (from-to)	1525-1527
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/c39830001525
Publication status	Published - 1983
Externally published	Yes

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Decker, M. J., Fjeldsted, D. O. K., Stobart, S. R., & Zaworotko, M. J. (1983). Weak intermetallic bonding. A rare example of molecular stacking in a neutral square-planar second-row transition-metal complex. X-ray crystal structures of [Rh(cod)(Cl)(dmpH)] and [Rh(CO)₂(Cl)(pzH)] (cod = cyclo-octa-1,5-diene; dmpH = 3,5-dimethylpyrazole; pzH = pyrazole). Journal of the Chemical Society, Chemical Communications, (24), 1525-1527. https://doi.org/10.1039/c39830001525

Decker, Michael J. ; Fjeldsted, D. O.Kimberley ; Stobart, Stephen R. et al. / Weak intermetallic bonding. A rare example of molecular stacking in a neutral square-planar second-row transition-metal complex. X-ray crystal structures of [Rh(cod)(Cl)(dmpH)] and [Rh(CO)₂(Cl)(pzH)] (cod = cyclo-octa-1,5-diene; dmpH = 3,5-dimethylpyrazole; pzH = pyrazole). In: Journal of the Chemical Society, Chemical Communications. 1983 ; No. 24. pp. 1525-1527.

@article{477c5fdf7ee04f048759a472cad7f176,

title = "Weak intermetallic bonding. A rare example of molecular stacking in a neutral square-planar second-row transition-metal complex. X-ray crystal structures of [Rh(cod)(Cl)(dmpH)] and [Rh(CO)2(Cl)(pzH)] (cod = cyclo-octa-1,5-diene; dmpH = 3,5-dimethylpyrazole; pzH = pyrazole)",

abstract = "The molecular geometry of [Rh(cod)(Cl)(dmpH)] (cod = cyclo-octa-1,5-diene; dmpH = 3,5-dimethylpyrazole) is normal in all respects with the heterocycle almost perpendicular to the Rh co-ordination plane and intermolecular Rh ⋯ Rh 4.49 {\AA}; by contrast the crystal structure of [Rh(CO) 2(Cl)(pzH)] (pzH = pyrazole) provides a classic example of molecular 'stacking', with Rh-Rh long at 3.4522(4) {\AA} along the one-dimensional chain.",

author = "Decker, \{Michael J.\} and Fjeldsted, \{D. O.Kimberley\} and Stobart, \{Stephen R.\} and Zaworotko, \{Michael J.\}",

year = "1983",

doi = "10.1039/c39830001525",

language = "English",

pages = "1525--1527",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

number = "24",

}

Decker, MJ, Fjeldsted, DOK, Stobart, SR & Zaworotko, MJ 1983, 'Weak intermetallic bonding. A rare example of molecular stacking in a neutral square-planar second-row transition-metal complex. X-ray crystal structures of [Rh(cod)(Cl)(dmpH)] and [Rh(CO)₂(Cl)(pzH)] (cod = cyclo-octa-1,5-diene; dmpH = 3,5-dimethylpyrazole; pzH = pyrazole)', Journal of the Chemical Society, Chemical Communications, no. 24, pp. 1525-1527. https://doi.org/10.1039/c39830001525

Weak intermetallic bonding. A rare example of molecular stacking in a neutral square-planar second-row transition-metal complex. X-ray crystal structures of [Rh(cod)(Cl)(dmpH)] and [Rh(CO)₂(Cl)(pzH)] (cod = cyclo-octa-1,5-diene; dmpH = 3,5-dimethylpyrazole; pzH = pyrazole). / Decker, Michael J.; Fjeldsted, D. O.Kimberley; Stobart, Stephen R. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 24, 1983, p. 1525-1527.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Weak intermetallic bonding. A rare example of molecular stacking in a neutral square-planar second-row transition-metal complex. X-ray crystal structures of [Rh(cod)(Cl)(dmpH)] and [Rh(CO)2(Cl)(pzH)] (cod = cyclo-octa-1,5-diene; dmpH = 3,5-dimethylpyrazole; pzH = pyrazole)

AU - Decker, Michael J.

AU - Fjeldsted, D. O.Kimberley

AU - Stobart, Stephen R.

AU - Zaworotko, Michael J.

PY - 1983

Y1 - 1983

N2 - The molecular geometry of [Rh(cod)(Cl)(dmpH)] (cod = cyclo-octa-1,5-diene; dmpH = 3,5-dimethylpyrazole) is normal in all respects with the heterocycle almost perpendicular to the Rh co-ordination plane and intermolecular Rh ⋯ Rh 4.49 Å; by contrast the crystal structure of [Rh(CO) 2(Cl)(pzH)] (pzH = pyrazole) provides a classic example of molecular 'stacking', with Rh-Rh long at 3.4522(4) Å along the one-dimensional chain.

AB - The molecular geometry of [Rh(cod)(Cl)(dmpH)] (cod = cyclo-octa-1,5-diene; dmpH = 3,5-dimethylpyrazole) is normal in all respects with the heterocycle almost perpendicular to the Rh co-ordination plane and intermolecular Rh ⋯ Rh 4.49 Å; by contrast the crystal structure of [Rh(CO) 2(Cl)(pzH)] (pzH = pyrazole) provides a classic example of molecular 'stacking', with Rh-Rh long at 3.4522(4) Å along the one-dimensional chain.

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